Great Depression

Mrs. Russell Cause and Effect Essay English 101-80 Great Depression What caused the Great Depression, the worst economic depression in US history? It was not just one factor, but instead a combination of domestic and worldwide conditions that led to the Great Depression. The causes aand effects of the Great Depression was huge across the world, here are three top causes and effects of the Great Depression. Stock Market Crash of 1929 was one of the major causes that led to the Great Depression.Two months after the original crash in October, stockholderzs had lost more than $40 billion dollars. By the end of 1930, the stock market tried to regain some of its losses but it was not enough and America truly entered the Great Depression. Throughout the 1930s, over 9,000 banks failed. Bank deposits were uninsured and thus as banks failed people simply lost their savings. Surviving banks was unsure of the economic situation and concerned for their own survival, stopped being as willing to cr eate new loans.This exacerbated the situation leadig to less and less expenditures. When the stock market crashed, and the banks failed and unemployment levels reached higher and higher pointsw people understandably stopped spending money, which also deeped the economic crisis as demand for products and services slowly stopped. First effect is Stock Market and Banking regulations, after the stock market crash of 1929 and collapse of more then 40% of American banks, strict trading and banking regulations put in place.For financial protection newly formed Securities and Exchange Commission and the Federal Deposit Insurance Corporation for financial protection. Second effect is when Franklin D. Roosevelt’s introduced programs between 1933 and 1930, designed to help America pull out of the Great Depression by addressing high rates of unemployment and poverty. FDR and Congress introduced regulationzs and subside: the cornerstones of the New Deal wetre the Public Works Administrati on and the National Recovery Administration.Third effect is when many people learned some valuable things about managing their money and doing the best they could with what they had. Children grew up to be very imaginative and inventive. They appreciated the things they had access to in their life because they never forgot just how little they once had. The Great Depression ended in the 1939 as the world increased the production of the war materials with the outbreak of WWII. War production increased jobs and hence large amounts of money were reintrodu ced to circuklate in the economy. Great Depression Steinbeck teaches us that as humans, loneliness and the desire for companionship is inevitable and in this cruel world where we are all set again t one another as rivals for the resources needed to survive, true friendships are to be cherisher d for they are hard to come by. As humans, we are all subject to loneliness at some points in our lives, and we all desire companionship, no matter how indifferent we may act to mask that desire. In by John Steinbeck, Curler's wife is incredibly lonely as the only woman on the ranch and is often isolated from the ranch hands who view her as trouble.She is often see n prancing around the ranch in the pretense of searching for her husband and often attempts to engage other ranch hands in friendly conversation. During her conversation in the stables with Car kooks, Candy, and Leonie, she remarked, ‘Effendi I don't like to talk to somebody ever' once in a w hill? Think like to stick in that house all time? â€Å"‘ (Steinbeck, 77). This was particularly imp rotary as it displays her loneliness and desire for companionship. However, her friendly sees is often seen as flirtatiousness to the other men, and this results in their view of her as an unfed dutiful and dangerous woman.Crooks, just like Curlers wife, suffers from loneliness as w ell, though his isolation results from his race instead of his words and actions. As shown during Eng his conversation with Leonie in the stables, Crooks remarks that â€Å"if he sees something', he don't know whether its right or not† and he has no one to ask and â€Å"nothing to measure by† (Steinbeck 73). He had also cried that if â€Å"a guy gets too lonely an' he gets sick† (Steinbeck 73). This was IM portent as well for it showed just how desperately we desire companionship.If we had no on e besides us, we get so lonely and desperate that we became sick due to the lack of company. The desire for companionship and loneliness are inevitable parts of human li fe that we all ex pertinence from time o time, though we may all deal with it in various methods, with some acting more indifferent than others. In this world with a population of around 7 billion and extremely limited ores urges, we are born into a dotage world. The competition for resources took a turn f or the worse when the Great Depression hit in the asses. Futures this harsh reality in which men are set against each other in a competition for the sparse jobs and machined De money, which was then used to purchase a piece of land. This was the dream of every men, but alas, in a world of worsening economy, very few saw their dream to fruition. As Curlers wife had observed in the novella, if she engaged one man in a conversation, they'd get along just if en and have a nice chat. However, if she attempts to engage a group of men in a conversation, the eyed all be too scared of each to talk to her, they'd be too scared that the others may â€Å"get so meeting' on them.This observat ion shows the hostility hidden beneath the pretense of friendly sees the men have with one another. The minute the rest â€Å"gets something† on one of the men, the eyed eliminate him so they'd have less competition for the resources, in this case, money and job s. When Candy, George, and Leonie were first entertaining the idea of owning a stake together r, George had warned them not to tell a soul for ‘they liable to can us so we can't make no SST aka† (Steinbeck 61 This warning displays the distrust among the men.Perhaps this is why true e friends pips are cherished and mourned when lost, for in this hostile world, it is difficult to co me by, but a great blessing in times of hardship. The world is cruel and hostile, and men are all says out to get one another. Loneliness and the desire for companionship is inevitable, we will all expire once it in our bedtime at one point or another, and it will only teach us to cherish our comma onions more.After all, true com panions are hard to come by in this harsh reality in which we are all born as rivals battling for the same limited resources we need to survive. Steinbeck had, thro cough his profound use and command of the English language, taught us, to put it in the simplest way, how to understand one another better. The key to communication and relations ammo Eng people is the understanding of each other, and through , Steinbeck has taught us just how we can begin to understand one another. Great Depression Mrs. Russell Cause and Effect Essay English 101-80 Great Depression What caused the Great Depression, the worst economic depression in US history? It was not just one factor, but instead a combination of domestic and worldwide conditions that led to the Great Depression. The causes aand effects of the Great Depression was huge across the world, here are three top causes and effects of the Great Depression. Stock Market Crash of 1929 was one of the major causes that led to the Great Depression.Two months after the original crash in October, stockholderzs had lost more than $40 billion dollars. By the end of 1930, the stock market tried to regain some of its losses but it was not enough and America truly entered the Great Depression. Throughout the 1930s, over 9,000 banks failed. Bank deposits were uninsured and thus as banks failed people simply lost their savings. Surviving banks was unsure of the economic situation and concerned for their own survival, stopped being as willing to cr eate new loans.This exacerbated the situation leadig to less and less expenditures. When the stock market crashed, and the banks failed and unemployment levels reached higher and higher pointsw people understandably stopped spending money, which also deeped the economic crisis as demand for products and services slowly stopped. First effect is Stock Market and Banking regulations, after the stock market crash of 1929 and collapse of more then 40% of American banks, strict trading and banking regulations put in place.For financial protection newly formed Securities and Exchange Commission and the Federal Deposit Insurance Corporation for financial protection. Second effect is when Franklin D. Roosevelt’s introduced programs between 1933 and 1930, designed to help America pull out of the Great Depression by addressing high rates of unemployment and poverty. FDR and Congress introduced regulationzs and subside: the cornerstones of the New Deal wetre the Public Works Administrati on and the National Recovery Administration.Third effect is when many people learned some valuable things about managing their money and doing the best they could with what they had. Children grew up to be very imaginative and inventive. They appreciated the things they had access to in their life because they never forgot just how little they once had. The Great Depression ended in the 1939 as the world increased the production of the war materials with the outbreak of WWII. War production increased jobs and hence large amounts of money were reintrodu ced to circuklate in the economy. Great Depression If someone went to prison in 1989 and was released in the year 2000, he would probably be surprised by how drastic change can be in ten years can bring. When 1990 started, people were still communicating through letters and the telephone. The Bible was still the greatest bestseller and people used the word â€Å"terror† to describe how scared they were of their neighbor’s dog. By the end of 1999, however, children were engrossed with a new book. People were sending e-mails to their loved ones, and our idea of terror has been redefined.The 90s was shaped by things we could not have imagined, things that have brought about major changes in our lives. Though the decade was made of numerous and note-worthy events, this paper will zero in on three factors that best define the 1990s in America: the story that mattered to the young, the technology that changed the face of communication, and the heartbreak that we suffered as a nation. In trying to define the 1990s in America, it is important that we take a look at the decade’s popular literary works. Literature is an important indicator of the times.By reading the popular literature of the early 1920s, we see a generation dried out by the. If we read the poetry and fiction of the Beat writers, we see a carefree generation of the late 50’s ready to break into the sexual revolution of the 60s. I’ve always thought of literature as a reflection of a people’s state of mind. It is, after all, the collection of stories of people. And people only write stories of the things that truly matter to them. Ironically, in the 90s, the most popular story ever told could not have happened to anyone.That would just be silly. No 11-year-old boy could have found out that he was a wizard and then went off to wizardry school. But that is exactly the premise of the most popular book of the 90s —Harry Potter. The premise does sound pretty simple, but author JK Rowling managed to craft intricat e storylines of various adventures, with mysteries being deliciously unraveled along the way. The result? The highest selling children’s book in history. No other children’s book has ever made much of an impact as â€Å"the boy who lived†.From then on there were several other books written about magic, wizards, vampires, robots, things not of this earth. And I think this is indicative of what we as a people are ready for. We are a generation ready to be bewildered, to consider things outside our immediate reality. Wiktorin, in his paper about how the Harry Potter books relate to contemporary life, states that â€Å"constructing a world different to the ordinary one and marketing this, can certainly be a very lucrative enterprise† (2). This is exactly what Harry Potter and all the fantasy books of the nineties have offered us.A constructed world so different from our own, but governed by the rules and emotions that are quintessentially human. This readines s to consider things outside our realm went hand in hand with the explosion of the internet in the nineties. In 1984, if you were a lonely kid in school, you went home and dealt with it. In 1998, a nerdy 13-year-old who probably feels ill at ease with his schoolmates can log in on the internet after school and find an online community of people to talk to. In the 1990s, the internet was really primarily used for communication.The e-mail and the chat functions were the most popular internet activities. A study conducted by Axel Franzen shows that email increases social involvement and regression analysis shows that Internet users have 24% more friends (Lesnard, 4). The world got a lot smaller, and getting in touch was just a few clicks away. The amount of information that the World Wide Web has brought to individuals cannot be emphasized enough. If Harry Potter led us to believe or consider things that are outside our realm, the internet allowed us to think of the things that existed beyond our personal reality.It allowed us to be tolerant of differences, because these differences are no longer miles away from us. We hear about it a few clicks away. The things that we can see on the internet can also be seen by people with internet in China. It equalizes us somehow and allows us to interact in astounding ways. As much as Harry Potter brought about a considerable amount of whimsical escape and the internet allowed us to be more aware of others’ cultures and differences, certain events of the 90s unfortunately gave us first-hand experience of evil.In the middle of the decade, America experienced its first terror attack through the Oklahoma Bombing. Despite the number of wars that have been fought by our country, a terror attack was so surprising because it just didn’t make sense. The Oklahoma bombing wasn’t an unfortunate result of any military operation. It wasn’t the work of some psychotic man. It wasn’t an accidental occurren ce. Rather, it was a carefully calculated plan with the sole purpose of terrorizing people. The perpetrators were apprehended and convicted, and the reasons behind their actions was said to be disappointment with how the U.S government handled past issues. Instead of letting their opinions known through protests, they took a course of action as arbitrary as it is terrorizing. The Oklahoma Bombing killed 108 people, including babies on daycare. This terrorist attack reminded us of the need for security, to protect our nation from people who are on the mission to destroy it. When it comes to vigilance against terrorism, â€Å"unlike most other enterprises, success and failure are measured according to the number of lives saved and lost† (Manzi, et. al. , 10).We cannot afford to lose the war against terror, as it will mean losing precious lives. After the Oklahoma bombing, the government implemented tighter security measures and that has stopped numerous other terror attempts. H owever there still continues to be groups of people who vehemently disagree with what America stands for as a nation. So much so, that they are willing to kill thousands of people just to show their hatred and defiance. Sadly, they succeeded again in 2001, when we found ourselves dealing with the horror that is 9/11.Every year we learn something new. Every decade stands for something. But during 1990s, aside from learning the Macarena and wearing baby doll dresses with high cut boots, aside from thinking that boy bands were actually cool, we grew a lot as a nation. The internet has shown us that the world as we know it could be perceived as an entirely different world for others. And it is important to be tolerant of differences, to respect differences. Terror attacks have shown us the extreme effects of our intolerance.Even the preferred choice of reading material shows that we are ready to tolerate changes, unlike Harry Pottter’s human family who can’t accept the fac t that he’s a wizard. There is still so much to be learned, so many virtues to put into practice, and knowledge to be put in use. But I’d love to believe that the experiences we had in the 90s helped us a lot. And in retrospect, I hope that I will also consider this decade as great as the one it preceded. Works Cited: Lesnard, L. †Social Change, Daily Life, and the Internet†, Chimera Working Paper, 2005-07: Retrieved on 17 November 2008, http://hal.archives-ouvertes. fr/docs/00/04/46/29/PDF/CWP-2005-07-Lesnard-Social-Change. pdf Wiktorin, Pierre. â€Å"Constructing a Distinct Other: Harry Potter and the Enchantment of the Future† 17 May 2005. Retrieved on 17 November 2008, http://www. anpere. net/2007/12. pdf Manzi, Powers, & Zetterlund. â€Å"Critical Information Flows in the Alfred P. Murrah Building Bombing: A Case Study†. The Terrorism Studies Series. Retrieved on 17 November 2008. http://www. mipt. org/pdf/murrahcasestudy. pdf

The Principle Of Accounting And Management Accounting Essay

Business moralss is of import in presents, as the human civilisation development. People ‘s life manner, public positions of event and the new engineering of media are non every bit same as before. All of the alterations are raising concern ethic onto a high degree importance for concern. Business in order to accomplish long-run net incomes, client relationship, it must utilize the moralss to curtail the duty ‘ ( Ferrell, Fraedrich & A ; Ferrell 2008 ) . For illustration, the recent events in Corporate America have demonstrated the destructive effects that occurs when the leading of a company does non act ethically, and concern savvy corporate professionals at Enron, Tyco, WorldCom, and Adelphia got themselves into such a large muss. The job lies in a profound deficiency of moralss. B ) ‘An ethical issue is a job, state of affairs, or chance that requires an single, group, or organisation to take among several actions that must be evaluated as right or incorrect, ethical or unethical. ‘ ( Ferrell, Fraedrich & A ; Ferrell 2008 ) For illustration, â€Å" Venkat as a database decision maker for a company found a memo about a co-worker acquiring sacked due to non working up to standard and holding a bad attitude. Venkat is shocked at this because this co-worker Tom is an built-in member of successful development of an object due to his working relationship with providers. And besides a best friend of Venkat, amongst general conversation Venkat finds out that Tom is about to suggest to his girlfriend and set a sedimentation on a new residential unit. † ( Blount 2008 ) For this instance the moralss issue is Venkat ‘s unity moving candidly and being straightforward towards Tom ( trueness to Tom as a friend ) VS trueness to tauten self involveme nt of maintaining his occupation. Ethical quandary ‘are a job, state of affairs, or chance that requires an single, group, or organisation to take among several incorrect or unethical actions that have no right or ethical picks, merely less unethical or illegal pick as perceived by any and all stakeholders. ‘ ( Ferrell, Fraedrich & A ; Ferrell 2008 ) it exists when two or more values are in struggle, and seek from moralss a declaration to this struggle. For the above instance the ethical quandary were: Tell Tom that he is about to be sacked, this affects Tom as he loses his occupation, Venkat as he may lose his occupation if company financess out he breach confidentiality and the company because Tom may sell confidential info or do malicious harm to their belongings. Keep silent, this affects Tom as he will lose occupation and be under fiscal force per unit areas, Venkat loses an built-in squad member. Company works more expeditiously and has better client dealingss. degree Celsius ) Ferrell stated the moralss issue or quandary is evidently, when the job is approximately opprobrious or intimidating behaviour, lying, struggles of involvement, graft, corporate intelligence, favoritism, sexual torment, environmental issue, fraud, insider trading, intellectual-property rights, and privateness issue. ( Ferrell, Fraedrich & A ; Ferrell 2008 ) The ethic issues ever occur with struggles of involvements, evaluated as right or incorrect, ethical or unethical. Let the organisation to seek from moralss a declaration to this struggle. So in an organisation the values of struggles are more impetuousness the issue and quandary is more evidently. vitamin D ) As the definition of moralss issue is a job, state of affairs, or chance. So it could non be kept inactive. Since moralss are made up of moral regulations and these regulations as different common jurisprudence, and different societies and civilizations have different set of moral codifications. â€Å" Merely like kids civilizations are exposed to different stimulation and that produces different personality aka Morals. Over clip a stimulation may impact a section of the population in such a dramatic manner that they change as a society their moral brand. † ( Wikipedia, 2009 ) . Now that construct is considered unethical, moral Ethic issues are alteration over clip.Question 2The four factors of ethical decision-making model are ethical issue strength, single factors, organisational factors and chance. ( Ferrell, Fraedrich & A ; Ferrell, 2010, p.122 ) . Ethical-issue strength can be defined as the perceptual experiences about ethical issue for single or group. It se ems like Jim had realize do non describe the bad waste goes into the river is unethical behaviour, because Jim was thought the factory ‘s waste disposal into the river did non exceeded Environmental Protection Agency ( EPA ) guideline, but when he knows the truth, he was amazed. As a director of Cinco, Jim has duty to maintain the works running ethically, environment pollution and payoff are ever serious ethical issues, non merely for Jim besides for Cinco Corporation. If factory was shutdown, many people in the town will lose their occupations, even a whole household, because in facts, the works boasts about employees whose male parent and grampss have besides worked at that place. This ethical issue is really of import to both Cinco and Jim. In a word, ethical-issue strength should be the indispensable factor in the ethical decision-making procedure ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 ) . Individual factors include instruction, nationality, age and venue of control ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 ) . Individual factors have more consequence on person ‘s behaviour, doing the difference among different persons. For Jim, he merely finishing the preparation plan, there is a lactiferous calling for him in the hereafter. What ‘s more, all of his predecessor wage for Ralph, and nil happened. Jim face both fire, but he have to take one. Ethical civilization displays whether the administration has an ethical scruples ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 p127 ) . Organizational factors conclude corporate civilization, obeisance to authorization and ethical civilization ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 ) . The organisation ‘s policy gives directors excessively much infinite and opportunity to things unethically, in another words-lack of control. As a consequence, it creates a hole in the company ‘s system so that Jim ‘s predecessor can utilize it to accomplish excess benefits, many other employees in the company besides have got benefit by making unethical behaviour, it reflects the corporate civilization. The last 1 is chance. It means the state of affairs in administrations that limit or permit ethical or unethical behavior ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010, p127 ) . Cinco Corporation merely focuses on public presentation and deficiency of supervising on procedure control. These features are in which create chance for directors to take unethical behavior. As a effect, Jim can make this without fright due to any regulations or penalties.Question 3a ) The organisations like PETCO faced with several ethical issues, such as 1 ) PETA think they sell or use animate beings for commercial intent, 2 ) mistreatment of animate beings, 3 ) clients found ill finches, a mouldy dead polo-neck, dead birds, and a frog â€Å" cooked to decease † and soaking clients on sale points, 4 ) sexual and other types of torment, drug maltreatment, plus protection and force, 5 ) struggle of involvement, 6 ) the credence of gifts and amusement B ) The definition of primary stakeholder could be who has direct influence with house ‘s endurance, which can be employees, clients, investors, and stockholders, besides include authoritiess and communities that provide necessary substructure ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 ) . For secondary stakeholder, it has non direct relationship with the house and has non critical effects on the house that include media, trade associations and special-interest groups ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 ) . PETA, as a special-interest group, it was focused on big animate beings, nevertheless, carnal gross revenues merely got 5 % of PETCO ‘ s gross, so PETA ‘ s unfavorable judgment had non indispensable for its endurance, what ‘s more, PETA besides did n't affect in PETCO ‘ s dealing. All of above shows PETA is a secondary stakeholder of PETCO. degree Celsius ) ‘Shareholder theoretical account of corporate administration is founded in authoritative economic principles, including the end of maximising wealth for investors and proprietors. ‘ ( Ferrell, Fraedrich & A ; Ferrell 2008 ) For keeping intent of public presentation answerability between top direction and the house ‘s stockholders, publically traded houses, corporate administration focuses on developing and bettering the formal. Stakeholder theoretical account of corporate administration ‘adopts a broader position of the intent of concern, although a company has a duty for economic success and viability to fulfill its shareholders, it besides must reply to other stakeholder, including employees, providers, authorities regulators, communities and particular involvement groups with which it interacts ‘ ( Ferrell, Fraedrich & A ; Ferrell 2008 ) . Comparer the two theoretical accounts, the truth is that the stockholder theoretical account is a more restrictive precursor to the stakeholder orientation. In this instance, PETOC is more focal point on stakeholder relationship development, so stakeholder theoretical account is better represented. vitamin D ) Social duty means organisation ought to maximise its positive consequence on stockholders and acquire the negative impact in lower limit, which besides includes four stairss, viz. , economic, legal, ethical and philanthropic ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 ) . The first measure is economic ; it is common sense that about organisations have a mark in the economic, doing the maximized net income. They have duty for their stakeholders who invest money on the organisation. Merely if the organisation makes great return for the stakeholders, they would wish to put more money. On other manus, economic besides includes support occupations in society and contribute goods and service to the economic system ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 ) . PETCO chose 12,000- to 15,000-square-foot shop that close local vicinity shopping finish as the chief format ; as a consequence, well locations will make big figure of net income. Besides, PETCO has 16,900 employees, 9,000 of which are full clip, assisting many people to work out their working job. What ‘s more, PETCO build up PETCO Foundation and other plans, like â€Å" Round up † , â€Å" Think Adoption First † . They donate in-kind goods and service to heighten the relationship between people and pets for valuable organisations. The 2nd measure is legal which means organisation should obey all Torahs and authorities ordinance ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 ) . PETCO besides fulfill this measure, for illustration, it encourage all associates should follow the accounting Torahs include the Sarbanes-Oxley Act and the by and large accepted accounting rules. The 3rd measure is ethical, which support rules and criterions to steer behaviour in the organisation ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 ) . In the PETCO, it has several ethical plans to standard employees and stakeholders ‘ behaviours. For illustration, it avoids strugg les of involvement among associates and has the codification of ethical to turn to the credence of gifts and amusement. The highest measure is beneficent. In this measure, organisation is encouraged to do part to the society by their ain determination ( Ferrell, OC, Fraedrich, J & A ; Ferrell, L, 2010 ) . PETCO does good in this facet through set uping foundations and plans. PETCO Foundation is one of the foundations to progress charitable, educational, and other philanthropic activities for the betterment of animate beings everyplace. The â€Å" Round Up † Program already raised $ 817,000 for local animal-welfare organisations in 2004. Beside them, PETCO besides has other plan contribute to philanthropic, such as, â€Å" Think Adoption First † , â€Å" Jumping a Pet † , â€Å" Tree of Hope † , â€Å" National Pet Adoption Days † and â€Å" Kind News † . Above all, PETCO already met the four degree of societal duty.Question 4In this inquiry, I would take ANZ bank from the Connect 4 Database to be analyzed as follows. It is stress on concern unity and professionalism, in order to run into the highest degrees of revelation and conformity. Through analyzing of the one-year study, it is could give a better of understanding how this company to obey the rules with ASX Governance. What will be concentrated on are Principle 2 and 4. The 2 rule is construction the board to add a value. Companies should hold a board of an effectual composing, size and committedness to adequately dispatch its duties and responsibilities. ( JIM PSAROS, 2009, p9 ) . This rule is aimed to set up a board in sensible construction so that the board is able to carry on their responsibilities efficaciously. ANZ used to finish the rule with Recommendation 2.1 A bulk of the board should be independent managers ( ASX Corporate Governance Council 2007, p10 ) . During the one-year study we can establish there are 10 managers in the board. Nine of them are independent managers, it besides stated that under appropriate state of affairss the managers, the board and the board commission are allowed to happen outside professional advice. It entree in appropriate fortunes to independent professional advice ( ANZ one-year study, 2009 ) Recommendation2.2. The chair should be an independent manager ( ASX Corporate Governance Council 2007, p17 the president of ANZ is a independent manager. He is besides a no-executive manager as good. He is responsible for leading of the board and for the efficient administration and behavior of the board ‘s operation. As the function in chair should ease the effectual part of all managers and advance constructive and respectful dealingss between managers and between board and direction. In the managers study of one-year study in ANZ it besides motioned they strict followed the function. ( ANZ one-year study, 2009 ) Recommendation 2.3 The function of chair and main executive officer should non be exercised by the same person ( ASX Corporate Governance Council 2007, p17 ) . During the one-year study, it province that the company divide the function of the president and the executive, The division of duties between the chair and the main executive officer should be agreed by the board and set out in a statement of place or authorization. They have different duty. ( ANZ one-year study, 2009 ) Recommendation 2.4 The board should set up a nomination commission ( ASX Corporate Governance Council 2007, p18 ) The board of ANZ besides delegate several commission such as administration commission, Human resources commission, hazard commission, audit commission and engineering commission. The board commission will hold a self-assessment to look into the completion of the responsibilities, ends and aims. They besides need to put the hereafter mark. ( ANZ one-year study, 2009, pp62-63 ) . Recommendation 2.5 Companies should unwrap the procedure for measuring the public presentation of the board, its commissions and single managers ( ASX Corporate Governance Council 2007, p19 ) . ANZ have public presentation ratings to look into the operation of the board, commissions and managers. This helps to guarantee the stockholders are able to maintain their value stable. ANZ present the ways that they evaluate assorted parties. In footings the rating of the non-executive managers. ANZ bank has an one-year reappraisal base to look into the completion of the responsibilities of managers. The president would keep a meeting with every single manager to look into the conformity of codification of behavior /ethics. The president will describe the item of the rating to the board or Governance commission. When the non- executive manager confront the re-selection. They will be given a opportunity to supply unwritten or written statement to bespeak the ground of rhenium -selection. Witho ut the non-executive manager, the Sus scrofas so will evaluation the statement harmonizing to the demand of public presentation to make up one's mind whether to hold the re-selection. In respect of the rating of the president of the board, the president of administration commission will confer with the managers to look into the public presentation of the president of the board harmonizing to the functions of the president of the board. Then, the president of administration commission will fix an overview study to the administration commission and the board. The president of board will have a study as a feedback. Recommendation 2.6 Companies should supply the information indicated in the Guide to describing on Principle 2 ( ASX Corporate Governance Council 2007, p20 ) .The board will be measure around 3 old ages. ANZ will ask for external facilitator to look into the public presentation of them so that the issues of the operation will be found. As an indicant of the rule, the ANZ-09-annual study reveals the experience, headers, former directorships, and the related item of the managers. The study besides indicates the attacks of the appraisal of the managers, commissions, board and presidents. The functions of presidents and the managers are besides explained in the study. Furthermore, the responsibilities and the policy of assorted commissions are shown in the study. ( ANZ one-year study, 2009 ) The rule 4 is to set up a construction to safeguard and scrutinize the unity of the fiscal coverage independently ( ASX Corporate Governance Council,2 vitamin E vitamin D n. ) The undertakings related to this rule are Recommendation 4.1: The board should set up an audit commission ( ASX Corporate Governance Council 2007, p25 ) The ANZ bank establishes an audit commission. The major responsibility of the commission is to scrutinize the fiscal coverage and scrutinizing rating. The commission makes assignment for the external audit party every bit good. The president of the commission is an expert in the fiscal country. He leads the operation of the commission, nevertheless, he does non hold any other add-on duty comparing to other members. ( ANZ one-year study, 2009 ) Recommendation 4.2: The audit commission should be structured so that it: consists merely of non-executive managers, consists of a bulk of independent managers, is chaired by an independent chair, who is non chair of the board 4 ) has at least three members ( ASX Corporate Governance Council 2007, p25 ) The construction of the audit commission have several cardinal characteristic. It consists of four members. All of them are independent, non-executive managers. Chairman, Mr. I J Macfarlane, is non the president of the board. ( ANZ one-year study, 2009 ) Recommendation 4.3: The audit commission should hold a formal charter ( ASX Corporate Governance Council 2007, p26 ) . The ANZ bank has a formal charter for the audit commission. For case, this charter requires that the member of the company must be financially liberated. They must non hold the nature to derive benefit from pull stringsing the fiscal study. The president of the company is an expert in fiscal. But he does non hold the power beyond other members of the commission. Recommendation 4.4: Companies should supply the information indicated in the Guide to describing on Principle 4 ( ASX Corporate Governance Council 2007, p27 ) . The duty and the manner of conductivity of audit commission are good reported in the one-year study. The members of the commission and their experience, including the limitation of the commission and president are good indicated in the study. However, the study merely mentioned that ANZ bank had a charter of the audit commission and several illustrations of it. There is no full tabular array of charter for the readers. ( ANZ one-year study, 2009 ) B ) Transparency means openness, communicating and answerability in general account. However, in concern, transparence could be described as revelations of related studies or executive procedures so that the direction of a company could be oversighted and governed by internal and external users or stakeholders in the concern group ( Hermalin & A ; Weisbach 2007 ) . As we know that a company dedicates to heighten its corporate administration, increasing transparence could be adopted, such as increasing unwraping demands particularly the fiscal revelation statements. Because corporate administration of a company is the system and procedures exercised and controlled by the corporation, like managers and direction, and besides trades with the relationship among stakeholders of the company, doing executive procedures or decision-making processs for the company transparent could heighten the administration of the corporation ( Hermalin & A ; Weisbach 2007 ) . There is existent illustration to demo that in order to manage the corporate dirts occurred in celebrated and large companies increasing disclosing demands has been one of the alterations to heighten the corporate administration advocated by authorities. For illustration, in US, the celebrated Enron dirts, Sarbanes-Oxley ( sox ) was adopted in response to the dirt and other administration failures and requires unwraping, â€Å" elaborate off-balance sheet funding and particular purpose entities † . So there exists positive relationship between transparence and corporate administration and transparence is increased for the object to heightening corporate administration. In the statements of ASX CGPR, most rules would turn to transparence. For illustration, in principle1, revelation of procedure for measuring public presentation of senior executives has been required and this would increase the transparence of the assessing processes to the populace. In priciple2, ASX addresses the transparence through unwraping the procedures for measuring the public presentation of the board, commissions and single managers, and elaborate information would be presented in the corporate administration subdivision of an one-year study, such as in the corporate administration statements portion of one-year study for Blackmores Ltd. And in rule 3 of ASX CGPR, the transparence is addressed during the process of showing the publicity of ethical and responsible decision-making. In other rules of ASX statements, transparence is besides presented by the demand for unwraping related exercise or executing procedures. For case in rule 5, 7 and 8, in order to do confidence for the conformity to related demands or ordinances, the letter writer company constabularies should be published and crystalline to internal and external users. Harmonizing to the old analysis, transparence is addressed throughout the conformity to the rules of ASX CGPR.

British Isles

The British Isles have nt ever been a separate portion of Europe. Long clip ago Britain was a portion of the European continent. Then about ten thousand old ages ago during the terminal of the last Ice Age, when the clime grew warmer, new rivers and sees were formed Europe easy moved into its present form. The ancient people of Britain were simple huntsmans and ate flesh of animate beings fruits, nuts, honey. They fished, and gathered oysters. They did nt hold a lasting topographic point of life and traveled from topographic point to topographic point, sheltering in caves. Then the British work forces have become the husbandmans. The Stone Age husbandman had the spots in the woods that covered most of Britain. He kept half-wild cowss and hogs in a wood and in Northern Scotland, free from woods, he kept sheep. By the terminal of the Stone Age ( 2000 BC ) metal was already being used. It was clip of the Invasion of Beaker people. They came from the Northern Europe. They used bronze and it was them, who started the edifice of Stone memorials at Stonehenge. Mining and trade were turning during the Bronze Age ( ab. 2000-500 BC ) . About 500 BC British people were larning how to smelt Fe. Iron tools had an advantage over bronzy 1s: they were much cheaper. The beginning of the Iron Age ( Bachelor of Arts. 400 BC ) British Isles were invaded by Celts armed with arms of Fe. They conquered Kent and much of Southern England. They imposed their linguistic communication on the indigens, its Gaelic signifier was used in Irelan vitamin D and Scotland, the Brythonic signifier in England and Wales. It was the Brythonic folk that gave its name to the whole state. The first history of Britain was written by an educated merchandiser from Morsel. He besides wrote the first description of the people, called Celts. He said they were a gentlefolk, skilled craftsman, who welcomed visitants. The most educated visitant of Britain described the British as a ferocious race. His name was Julius Caesar. Present English dates back to 5th-6th centuries, when Germanic folk of Jutes, Saxons Angles overran all England except Cornwall Cumberland. Some spiritual footings were borrowed from Latin in connexion with change overing England to Christianity by St. Augustin. Some parts of England were invaded by Danes Norwegians, that s why the linguistic communications of the Anglo-Saxons Danes formed the footing of English. Jessye normans contributed greatly to the development of English linguistic communication during their invasion. Following point of this was the 15th-16th centuries when written linguistic communication was stabilized with aid of distributing of printing. In 19th century the growing of British colonial power led to the spread of English as universe linguistic communication. But still it was merely the 1930 when the British Foreign Office stopped utilizing French for all its official memorandum. So It was the long manner of coming-to-be the linguistic communication of international communicating from old Anglo-saxon idioms to the universe linguistic communication in twentieth century.

Alternatives to Simple Incarceration Essay Example | Topics and Well Written Essays - 750 words

Alternatives to Simple Incarceration - Essay Example Keeping such a large number of people in confinement is proving to be a financial strain on governments. Many first time offenders and people like Joe Jones who are not a threat to public safety can be safely integrated into the society under supervision. This will definitely save a lot of tax payer's money and will contribute positively to the rehabilitation of the offender. Having seen many people like Joe Jones during my tenure, I feel that it is high time for an alternative to be introduced into the system. A system can be devised which will take into consideration the public's point of view, the concerns of the government and the situation of the offender. Paramount focus should be given to public safety. For this an Electronic Monitoring Program1 can be introduced so that the offender will be under surveillance 24 hrs a day. This can be affected by fitting the offender with a tamper sensitive ankle or wrist device, which along with the telephone line will keep the authorities informed about the whereabouts of the offender. Public safety can be ensured by this step. ... Moreover this system can reduce recidivism (Joan Petersilia, Minimizing Harm as a Goal for Crime Policy in California, http://www.ucop.edu/cprc/rubin.html). One California study has shown a two third decrease in crime rates after implementing such a program. Not only should the offenders be put under surveillance, but they should be subjected to rehabilitative treatments (in the case of substance abusers), employment programs, easy access to specific types of counselling etc. They should even be encouraged to further their studies in course of the probationary period. This will definitely help in their reintroduction into society. Another advantage is that these programs will keep the offenders busy, leaving them with no or very little time to get lured back to crime. Joe Jones Joe Jones wants to make amendments for his actions and put all of this behind him. I will present him with the alternate program where he will not have to spend time in prison, but attend employment programs, offer community services etc, while having the option to further his studies. Since he wants to repay his victims, he may draft a letter to each of them, apologizing for his actions and conveying his sincere wish to repay them. I myself will have to explain to the victims the reason for Joe not spending time in prison. I will have to explain how the issue of public safety has been addressed in this program. Also how this program will benefit Joe Jones and in due course the victims themselves, when Joe will finally be able to repay them. Public awareness of the Alternative Program is very important for the success of the program. So enlightening the victims about the course of action taken against the offender is an integral part of successfully

Music assignments Assignment Example | Topics and Well Written Essays - 500 words

Music assignments - Assignment Example The introductory part of the prelude to The Afternoon of a Faun has prominent parts of the harp and wind instruments. A unique feeling is created by the chromatic note sequence of the wind instrument heard in the initial stages of the Prelude. Derived harmonies and derived chords of namely 7ths, 9ths, augmented and diminished are heard creating a spectacular feeling of peace and anticipation at the same time. The feeling of the time of the day i.e., Afternoon is uniquely and clearly brought out. The song through unusual note sequence and mood changing notes introduced at the demarcation point of the stanzas of the musical piece creates a journey on its own. The undulating tone and progression and regression of notes introduce the feeling of being close to nature and natural cycles. The Afternoon of a Faun represents many feelings, peace, satisfaction, relief, fear, quest, confusion and relaxation. Quite unique and characteristic to Claude Debussy, his work is in this piece is characterised by unconventional rise and fall of tempo, intensity and notes. It involves the waxing and waning of the overall mood that the composition tries to convey. A rhythmic variation is also noticed towards the middle for the composition where stringed instruments dominant for most of the part. Claude Debussy’s unexpected harmony of strings and thought provoking combination of notes are seen in the background sequences that fill up the musical piece. The signature line of the musical piece shows Debussy’s ability to skilfully blend discordant notes into a mystical harmony and give it a life like affect. The signature line has the alternating major and minor chords playing. Debussy’s sight variation of the opening material is revealed toward the end with sharp clarinet sequences, differing in tempo, rhythm, timbre and overall texture. It is

Alberta's economic reliance on its energy resources Term Paper

Alberta's economic reliance on its energy resources - Term Paper Example In 1991, the overall industry construction had risen to thirty six percent. In addition, Alberta’s energy companies have also been affected by downsizing among Alberta’s oil and gas firms. The positive news about the energy sector is that their balance sheets are improving through debt reduction. Job insecurity is another factor that is affecting Alberta’s economy2. According to a recent research, statistics show that one out of four Canadians is concerned with the increasing job security. This job insecurity concern extends to both the white collar and the blue collar workers, which in turn reduces economic recovery. More intense research about Alberta’s work force claims that Albertans are the most highly educated workforce in Canada. The research went ahead to reveal that thirty eight percent of these individuals hold on the same job for over two years while the other percentage change jobs within the same period of time. Human resource capabilities are the most important factor that should arise to determine the long-term welfare of Alberta’s work force welfare. This paper will outline Alberta’s diversification progress and review other areas that are still lagging behind that needs improvement. Summary This article presents how Alberta’s economy gradually evolved. ... Ideally, the article presents how these economic set backs are affecting the society and the government has embraced these facts because the government is trying hard to curb these issues. Alberta’s poor economic growth is mainly contributed by poor infrastructure because it is only through proper infrastructure that the other economic sectors will open up. The best change to fix this problem is reconstructing all the necessary transportation roads. This will be possible if the concerned parties pile up pressure on the government to allocate a certain percentage of revenue to fix infrastructure. In contrast, the article â€Å"Alberta’s perspective†, seems to base its facts on the necessity of improving infrastructure because it is the gateway to the other economic developments. However, other alternatives are needed to collaborate with infrastructure to improve Alberta’s economy. Most of Alberta’s economic sectors depend on each other and that is wh y infrastructure alone cannot solve Alberta’s poor economy. For instance, agriculture will depend infrastructure and marketing skills in order to venture into the market. Therefore despite the fact that the author is basing his facts on infrastructure, I believe that other alternatives are needed. Therefore, the government should act fast by forming a delegation that will discuss Alberta’s reforms like, taxation system, reduce government spending and diversify Alberta’s energy global markets. Further, the supply of labor and the wage rate help determine the labor market equilibrium3. All of these strategies will only be a short term proposal intended on regaining back the economy. This is a temporal solution while

Coca-Cola Essay Example | Topics and Well Written Essays - 2250 words

Coca-Cola - Essay Example Much of the similarity in the culture has to do with the company’s mission and values that they truly appreciate. The paper will go much in detail about the Coca-Cola Company’s culture. Some topics will be on teams and how these are enforced within the company and how the culture helps motivate employees to achieve the company’s goals. The paper will also explain to some extent how the companies values are integrated in their culture which helps employees adhere to the same values. It helps gain understanding of whether the policies of the company contribute to the sustaining and nurturing of effective team roles and how that can lead to the rise and management of potential conflicts in the company. Corporate Culture Affecting Individuals and Groups and Organization’s Performance Corporate Culture of a business firm shapes the process of conducting business operations and activities. It signifies the different types of behaviors and relationship patterns r eflected by the business enterprise in the course of dealing with its internal and external stakeholders and organizational people. The business culture of Coca-Cola encompasses the parameters of integrity, passion, empowerment, commitment and diversity as the key standpoints in motivating the people to work in a spirited fashion. The organizational culture of Coca-Cola ignites the passion within the individuals to perform in an exalted fashion so as to continually work to promote creativity and innovation in their job pursuits. The people also work as Change Agents in the enterprise domain (â€Å"Our people, culture, vision and values†; â€Å"Workplace Culture†). To this end the above cultural paradigms of Coca-Cola tend to have an impact on the Job Performance criterion of the people in the concern. Job Performance is defined as the effective value gained from the different behavioral reflections of the employees that in turn tend to have an impact, positive or negat ive pertaining to the mode of accomplishment of organizational goals. Though these behavioral sets can be effectively controlled by the individual employees yet individual behavioral types like ‘Task Performer’ and ‘Citizenship Behavior’ are related as such that help in the effective goal accomplishments while ‘Counterproductive Behavior’ is taken to negatively impact the goal accomplishment function. ‘Task Performers’ and ‘Citizenship Behaviors’ are those employees that proactively work to transform the resources available with the concern in the form of technology, human and financial capital to produce desired set of goods and services and those that without any need for earning rewards move to form effective interpersonal relationships with other organizational people and also such that tend to defend the concern and boost the motivation levels respectively (Colquitt, LePine and Wesson 37-50). The work culture of C oca Cola encourages people to actively work in an empowered fashion to help accomplish organizational goals effectively. Moreover, the business culture of the firm being open motivates the people to work in a coordinated fashion to achieve end goals. In terms of Applications of Performance Management, the management team at Coca-Cola tends to work on the process of Management by Objectives where the employees mutually coordinate with their managers to perform a given set of objectives within a stipulated time period. Evaluation of the performance of the

Review and analyze John Updike's portrayal of the American middle Essay

Review and analyze John Updike's portrayal of the American middle class in his fiction - Essay Example So successful was his original representation of Rabbit Angstrom in his 1960 that he published two subsequent novels that followed the development of his character in both the 1970’s and the 1980’s. These novels describe many themes and motifs that were, and to a large extent still are, experienced by middle-class America. Accordingly, this brief essay will analyze some of these themes by considering key progressions that manifested themselves within two of John Updike’s novels. The first of these novels, Rabbit, Run, deals with the dissatisfaction that hid very casually beneath the surface of late 1950’s America. The topic is hardly ever discussed due to the fact that the post war years have been so highly stylized and idealized that the reader would think that not a care in the world existed (besides perhaps the Soviets and the bomb). Yet, within this seeming idyllic world, Updike portrays the life of the middle class, via the character of Rabbit Angstro m, as one which is fundamentally dissatisfied by the superficial consumerism and fraudulence that the late 1950’s had on the society of that time (Edwards 13). ... o the reader is one that engages the audience on a host of rather un-kosher topics (at least for the 1950s) with relation to abortion, prostitution, homosexuality, and even the topic of blow jobs. In this way, Updike is able to present to the reader, via the vehicle of Rabbit Angstrom, the frustration, confusion, despair, and ultimate desire for experience and sexual revolution that typified the generation of the late 1950s and early 1960s. As such, this representation was indicative of what would come to fruition during the 1960s and the cultural and sexual revolutions that re-defined the American landscape (Clasen 134). In this way, more than a running commentary on the factors that led to the growth and development of the American society during the period, Updike’s novel engages the reader with the understanding that fundamental dissatisfaction and unhappiness were the underlying reasons why the developments of the proceeding decades developed in the way they did. Similarl y, the second book in the series, published in 1971 and named Rabbit Redux, follows the same character, Rabbit Angstrom, and develops upon he and his deteriorating personal life and relationships that it has spawned. Rather than relating that the liberation of the 1960s has brought Rabbit the comfort, meaning and solace that he so desired in the first novel, the author relates that Rabbits life is very much incomplete in much the same way it was in the first novel (Crowe 83). Rabbit is still working a dead-end job, still quite unfulfilled, and has recently had his wife leave him. However, such a situation is not indicative of the middle-class struggle that Americans of this particular era were going through. As a means to engage the reader on the struggles that the middle class experienced in

What Role does Early Education Play in the 'Gendering ' of Children Essay

What Role does Early Education Play in the 'Gendering ' of Children - Essay Example As the report declares the gender bias can also impact access to educational equality, stifle their psychological and physical wellbeing. It is very critical for the early childhood educators to be conscious of the effects of stereotypes. The gender identity concept awareness is important for the educators because it is always placed on the children at a very early age, for example, nursery colors selection. Children start to understand and form gender concept at about two years of age. Most children begin to know they are a boy or a girl at the age of three years. At around three to five years, the children grow their gender identity and start to clearly understand male or a female traits. Immediately these young children understand their gender identity, they begin to develop gender stereotypes. From the research it is clear that gender is different between cultures and they are not necessarily the biological traits which differentiate between a male and a female. Earlier research has indicated that gender identification can be formed in two different perspectives; sex role theories and gender relational theories. The children are motivated to join the opposite sex areas out of their own choice, adopt nontraditional behaviours and attitudes. Gender relational theories, on the other hand, children are viewed to actively engage in their own gender identities. Gender in children is thought to grow continuously, based and shaped by ethnicity, the social class, culture, age and religion.

The ultimate nightmare Essay Example for Free

The ultimate nightmare Essay I lay down and waited for the soothing blanket of sleep shroud me. A few seconds later the anticipated blackness of slumber settled in†¦ Suddenly, the deafening noise of the alarm clock woke me up with a startling jolt. It seemed as though I had fallen asleep mere seconds ago and as I groggily looked around something did not seem right. The room looked the same as it did before I went to sleep. In the bright orange light that seemed to come from hells keep itself, shown through the flimsy curtains from the eerily noiseless street behind our house I could see that nothing was amiss. Nothing that I could notice straight away that is. As I got up from my bed, I saw that my sister was not in hers. I looked around once more, as the feeling of peculiar alarm and angst worked from the top of my head to the tips of my toes. I was at once perturbed and shaken as I saw that the room was clean, severely clean. There was naught on the tables, or in the wardrobe, not dust nor a shadow of the things that had been there and as I turned to look at the alarm clock, I was only more agitated to find the side table to be glimmeringly spotless. As the twisted black feeling of fear grew, I knew I had to go through the entire house. Having no idea of what time it was; except that it was dark; sinister as any night in a horror movie outside, I went through each and every room in our house only to find all of them stripped bare, like a newborn baby, from the ceiling to the floor. It was as though it had taken hours for me to do that, for me to find all my families things, my family, itself to have, disappeared like they had never existed in the first place. The fear that had been lit now consumed me like a wild fire. That this dream like situation that seemed to go on for hours only fed it. The fact that I now knew this was not reality but a horrifying nightmare did not seem any less daunting than if a dragon breathing fire had been placed in front of me. For this was my ultimate nightmare, to be left alone with not a thing in the world but worse than that that there was no one for me to go to. I could not do anything but wait in the spine-tingling prison like dream, wait for someone to wake me up, when, the shrill voice of the alarm sought me out,  again†¦

Stabilization of Nitrous Acid

Stabilization of Nitrous Acid Abstract Nitrous acid (HNO2) was stabilized via supporting on Polyvinylpolypyrrolidone (PVPP) and the thermal stabilization and structure were estimated using thermogravimetric analysis measurement and spectroscopic methods, respectively. Some novel heterocyclic azo dyes were synthesized by selective diazotization of aromatic amines followed by coupling with some susceptible aromatic compounds. The stereochemistry structure of the synthesized dyes were optimized using B3LYP at 6-311 G(d,p) basis set and their electron excitation properties were evaluated using calculations of density functional theory. UV-Visible analysis was applied for Photophysical properties evaluation of the new dyes and compared with computed vertical excitation obtained from TD-DFT. Also, the azo-hydrazone tautomerism of the triazine azo dyes was investigated and the results show that for all of the synthesized dyes both azo and hydrazone tautomeric forms exist, while 3a-5 shows more notable hydrazone form than others. Keywords: Polyvinylpolypyrrolidone, Nitrous acid, Azo dyes, azo-hydrazone tautomerism 1. Introduction Nitrous acid as a weak inorganic acid has significant applications in organic reactions such as diazotization, nitrosonation and Sandmeyer Reaction,[1,2] but its instability in temperatures upper 5  °C causes some restrictions to using it. In this work, we stabilized nitrous acid via supporting on polyvinylpolypyrrolidone (PVPP) and then utilized it in synthesis of some novel azo dyes. However, PVPP has been reported as an efficient support in many cases such as trifluoroboride and nitric acid.[3,4] PVPP-HNO2 has many advantages that make it environmentally acceptable in both industrial and laboratory viewpoints. It is applicable for a long time after preparation and the polymer easily remove by washing with water. In particular, nitrous acid absorbed on polyvinylpolypyrrolidone takes part in azo coupling reaction and the polymer remains almost completely intact. However, the literature describing arylamines conversion to diazonium salts using polyvinylpolypyrrolidone supported nitrous acid (PVPP-HNO2) is not available. Herein, we wish to present a convenient procedure for diazotization reaction using this stable reagent. Azo colorants from aromatic heterocyclic amines have sublimation fastness, excellent light and color strength.[5] They are one of the important groups of synthetic organic dyes. They are applied in various fields such as electronic photography, liquid crystal displays, paper printing, bleaching, polymers, laser technology, dyeing, color formers, data storage and solar energy conversion.[6] They also have been known as antibacterial, antifungal and anti-tumor compounds.[7,8] The compound 1,3,5-triazine has an alternative six-membered heterocyclic ring with an equal number of nitrogen and carbon atoms.[9] The triazines are analogues of benzene rings, which makes them as an aromatic compound like benzene. 1,3,5-Triazine, a common reagent which is used as herbicides and pharmaceuticals.[9] The diazonium salts of triazines derivatives have been reported as a diazotization targets in the synthesis of a variety of heterocyclic azo dyes[10,11] but no report found in direct diazotization of triazines with more than one aromatic amine group. The existence of azo-hydrazone equilibrium in azo colorants having the hydroxyl group at ortho or para position to azo linkage was proved in 1983.[12] In hydrazone form, due to the hydrogen bonding, a coplanar six-membered ring is formed with higher thermal stability than azo form ones.[13] After reductive cleavage, the azo chromophoric system gives carcinogenic amines,[14] while in the hydrazone tautomer will be cleaved the C-N bond instead of N=N bond.[15] The study of azo-hydrazone tautomerism gives the great information for degradation of azo chromophores with least toxicological effect on the environment. Finally, we report preparation of polyvinylpolypyrrolidone supported nitrous acid (PVPP-HNO2) and synthesis of novel azo dyes by diazotization of 6-phenyl-1,3,5-triazine-2,4-diamine (1)and 1,3,5-triazine-2,4,6-triamine (2), followed by coupling with hydroxyl and amine substituted of aromatic compounds (Scheme 1). The absorption spectra were obtained using a UV-Visible spectrophotometer and the structures of the triazine azo dyes were confirmed by spectral analysis. Also, DFT calculation was used for study of their azo-hydrazone tautomerism. The structures in azo and hydrazone forms were optimized in the TD-SCF method using B3LYP/6-311 G(d,p) basis sets. 3. Results and discussions 3.1. Stabilization of HNO2 over PVPP PVPP-HNO2 was prepared by a simple route. As regards the nitrous acid is extremely unstable in temperatures over than 5  °C, polyvinylpolypyrrolidone which previously has been applied as an efficient support,[3,4] was used and the spectroscopic and experimental results showed that PVPP can stabilize nitrous acid by formation of PVPP-HNO2. Thermal gravimetric analysis (TGA) investigation of the polymer and PVPP-HNO2 was performed to study their thermal stability (Fig. 1). The thermal decomposition of PVPP starts at near 330  °C and a sharp burning of polymer chains in pure PVPP sample occurs between 360  °C with the weight loss of ~75% of the initial weight. TGA spectra of PVPP-HNO2 demonstrate a mass degradation at 70  °C in PVPP-HNO2, whereas there is no similar situation in TGA spectra of pure PVPP. In other words, TGA spectra of PVPP-HNO2 show that stability of nitrous acid has been increased to 70  °C.   Due to that, the probable hydrogen bonding causes the stability of nitrous acid via prevention of its decomposition to nitrogen oxides. Furthermore the results of acid-base titration show that the PVPP-HNO2 is clearly more acidic than pure PVPP. While pH of the 0.1% solution of PVPP in water is about 7.0, but the same of PVPP-HNO2 is about 2.92. In other word, [H+] is 1.2ÃÆ'-10-3 M and it shows that [HNO2] is about 0.0032 M and it reveals there is about 0.02 g of nitrous acid in 1 g of PVPP-HNO2 which shows good accordance with TGA results. PVPP-HNO2 was prepared in different ratios of PVPP and HNO2.The best result that showed the maximum capacity of acid in the polymer was 20% w/w. The ratios determined by acid-base titration was consistent with TGA degradation analysis. Besides, the synthesis of PVPP-HNO2 was confirmed by FT-IR spectrum. It shows carbonyl band at 1658 cm-1, whereas the same band in pure PVPP has appeared at 1668 cm-1. This can attribute to hydrogen bonding between nitrous acid and PVPP (Figure 2). This type of interaction has been reported between PVPP and polyphenols.[16] The existence of the N-O band stretching at 1380 and 1572 cm-1 in PVPP-HNO2 and absence of this band on PVPP, gives the indication that nitrous acid has been linked to PVPP polymer (Figure 3). 3.2. Synthesis and characterization of azo dyes A simple and facile synthetic route was presented for the preparation of triazine azo dyes. We found that these products can participate in azo coupling reaction to form various and already known azo dyes. Therefore, we treated diazonium salts with 1-naphtol, 2-naphtol and other amino and hydroxy aromatic compounds to obtain a variety of azo dyes in good yields. The compound 4-amino-6-phenyl-1,3,5-triazine-2-diazonium was synthesized from mixture of 6-phenyl-1,3,5-triazine-2,4-diamine (1)and PVPP-HNO2 in 1 mmol of diamine to 2.0 g of PVPP-HNO2 ratio and further coupled with 1 mmol of 2-naphthol in DMSO to obtain 1-((4-amino-6-phenyl-1,3,5-triazin-2-yl)diazenyl)naphthalen-2-ol (3a-2)in good yield. Other derivatives have been synthesized by different coupling components (Scheme 2). The chemical structure of the new dyes was confirmed by 1H and 13C NMR spectroscopy. 2-naphtholic dyes 3a-2 and 3b-2 contain the hydroxyl group at ortho-position to the azo bridge and have the susceptibility to make a six-membered ring due to intramolecular hydrogen transfer. The result of this type of interaction is chemical shift deshielding of hydroxyl group proton than usual. 1H NMR spectra summarized in Table 1 indicates the dye 3a-5 shows an extra singlet at ÃŽÂ ´ 12.11 ppm attributed to N-H proton which is in hydrazone form.   The protons of NH2 in the heterocyclic ring of series 3a show singlet peaks at ÃŽÂ ´ 8.16 to 8.63 ppm while the same at series 3b appear at ÃŽÂ ´ 6.77 to 6.99 ppm. The 13C NMR spectrum of heterocyclic ring carbons shows down field peaks at ÃŽÂ ´ 180-190 ppm. Except compound 3a-4 which have three non-aromatic carbons, all of the other compounds just have aromatic carbons. 13C NMR spectrum of 3a-4 shows two peaks at ÃŽÂ ´ 96.2 and 151 .3 ppm that attributed to the carbons which have been linked to azo group and the hydroxyl group, respectively and a peak at ÃŽÂ ´ 162.0 ppm which assigned as ester carbon of coumarin ring. Infrared spectra of the synthesized chromophores show the band at 1500-1570 cm-1 related to the N=N bond.   A unique band at 2200 cm-1 in 3a-5 reveals the existence of C=N group which can be another evidence for the existence of hydrazone form in this compound. Electron ionization mass spectroscopy (EI-MS) was used to verify structure of the synthesized azo dyes. The base peak in all of the dyes is due to fragmentation of the molecules in the azo bridge. Series 3a and 3b show a base peak at m/z 171 and 110, respectively which attributed to the ionized heterocyclic rings. 3.3. Photo-physical properties and solvent effects To find out the color properties with structural correlation of the synthesized azo dyes, UV-Visible spectra of the dyes were recorded in solvents such as n-hexane, ethanol, acetonitrile and dimethyl sulfoxide at concentration of ~10-4 M and at room temperature. The results are tabulated in Table 1. Although a moderate bathochromic shift in ethanol and acetonitrile was seen, but generally no significant bathochromic shift was observed.  Ãƒâ€šÃ‚   The UV-Vis absorption spectra of all of the dyes in all solvents show the main band at 290-330 nm which can be assigned to moderate energy transition of the aromatic ring. All of the 3b series and compounds 3a-2, 3a-4 and 3a-5 in all solvents, two bands are displayed arising from the à Ã¢â€š ¬Ãƒ ¢Ã¢â‚¬  Ã¢â‚¬â„¢Ãƒ Ã¢â€š ¬* transitions in the backbone. The second bands appear at 360-500 nm can be assigned to azo bridge or intermolecular azo-aromatic chromophore. 3.4. Computational study: Gaussian 03 program package was employed to study Time-Dependent Density Functional Theory (TD-DFT) and the profusion of the synthesized azo dyes in their azo and hydrazone tautomeric forms.[17] TD-DFT calculations were applied using B3LYP/6-311 G(d,p) basis set with the default convergence criteria and without any limitation on the geometry. The TD-DFT provide the most powerful and effective computational tool for examining the ground and excited state properties of the azo molecules compared with obtained UV-Vis data. Time-dependent DFT method was applied for determination of the UV-Vis spectra, electronic transitions, and vertical excitation energies. 3.4.1. UV-Vis spectral analysis The UV-Vis spectra of azo dyes molecules were measured in dimethyl sulfoxide solution as shown in Figure 4. The calculated absorption maximum wavelength (ÃŽÂ »max), electron transition energies and oscillator strength both in solvent phase (DMSO as solvent) along with recorded UV-Visible data are shown in tables 2 and 3. The main characteristic of the spectra is determined by the general structure of the molecules. Each molecule has a double band Nà ¢Ã¢â‚¬ ¢Ã‚ N (azo group) which is directly conjugated with a homocyclic and heterocyclic aromatic ring. This group has a wide electronic delocalization. Therefore, it is possible to predict the presence of the main absorption band associated to a à Ã¢â€š ¬-delocalized system that involves the fragment Nà ¢Ã¢â‚¬ ¢Ã‚ N and other associated internal transitions that emerge from the aromatic and/or heterocyclic system. In this sense and in according with the structure of the compounds, we can determine that the first absorption band ÃŽÂ »1 located in the range of 290-320 nm with low intensity that appears as shoulder is attributed to à Ã¢â€š ¬Ãƒ ¢Ã¢â‚¬  Ã¢â‚¬â„¢Ãƒ Ã¢â€š ¬* transition that involves the aromatic rings, while the second absorption band ÃŽÂ »2 located in the range of 300-400 nm, attributed to a à Ã¢â€š ¬Ãƒ ¢Ã¢â‚¬  Ã¢â‚¬â„¢ à Ã¢ ‚ ¬* transition. This transition involves the azo bridge. The remaining absorption band located at lower energy corresponds to ÃŽÂ »3 and is assigned as the type nà ¢Ã¢â‚¬  Ã¢â‚¬â„¢ à Ã¢â€š ¬* transition. A similar behavior of the previous transition is observed. In tables 2 and 3, the experimental and calculated maximum absorption and the corresponding orbital contribution are shown. As observed, shorter wavelengths (ÃŽÂ »1) and in some cases ÃŽÂ »2 belong to lower occupied MOs such as HOMO-4, HOMO-6 and HOMO-8 and LUMO while longer wavelengths (ÃŽÂ »3) involves frontier molecular orbitals (FMOs). The description of FMO will be discussed in the DFT section. An example of the involved MOs for compound 3a-2 is presented in Figure 5. The entire former assignations were corroborated using TD-DFT calculations. The involved MOs for all of the synthesized compounds are presented in Figure S1-9. 3.4.2. DFT calculations For prediction of the molecules electronic spectra, the TD-DFT calculation is used because of low computational cost and high accuracy. The electronic structure of the molecule in ground state can be determined from the wave function of the electron moving within molecule because molecular orbital can be treated as electron channels.[18] The Gauss View program is applied to calculate group contribution of molecular orbitals, i.e. the highest occupied molecular orbitals (HOMOs) and lowest unoccupied molecular orbitals (LUMOs). In almost every calculated transitions, the FMO are involved, vide supra. The FMO of all compounds shows similar characteristics as observed in supplementary data (Fig. S1-9). In all cases, HOMO is delocalized over the homo-aromatic ring and azo bridge. The HOMO-1 is composed in every case mainly by the azo bridge. In terms of unoccupied MOs, the LUMO is mainly centered over the homocyclic and heterocyclic aromatic rings and azo bridge. On the other hand LUMO+1 of naphtholic compounds 3a-1, 3a-2, 3b-1 and 3b-2 is located almost over the triazine ring while in other compounds, LUMO+1 attributed to non-triazine aromatic rings. The ionization potential (IP), electron affinity and GAP energies do not follow any trend and the calculated values are similar and do not depend on the substituted coupled to triazine rings.[19] The estimated reactivity indexes such as chemical potential (ÃŽÂ ¼), chemical hardness (ÃŽÂ ·) and electrophilicity (à Ã¢â‚¬ °) are reported for make the approach of the potential reactivity of these synthesized dyes (Table 4). Chemical hardness is a measure of the resistance of chemical species to change its electronic configuration.[19] It is an index of the stability and chemical reactivity of compounds. The highest value of ÃŽÂ · is shown by compounds 3a-5 and 3b-4 in 3a and 3b series, respectively, which have 2-nitroaniline as coupling aromatic agent and are the most electron attracting substituent. On the other hand, the smallest value is shown by 3a-2 and 3b-2 which have 2-naphtol in the structure as a good electron-donor substituent. Chemical potential characterizes the tendency of escaping of electrons from the equilibrium system.[19,20] This index shows an opposite behavior to that of ÃŽÂ ·, where the highest value belongs to 3a-2 and 3b-2 which have electron donor substituent and the smallest value is shown by 3a-1 and 3b-4 which the second compound acts as an electron acceptor substituent while the first can acts as an electron acceptor via induction. Electrophilicity index (à Ã¢â‚¬ °) c ould give information comparing two in which one is nucleophile/electrophile via lower/higher à Ã¢â‚¬ °.[20] For example comparing between 3a-1 and 3a-2 shows that 3a-1 has higher à Ã¢â‚¬ ° and it can attribute to more electron attraction of 4-hydroxy substituent rather than 2-hydroxy in the naphtholic system. Another attractive comparison between 3a-1 and 3b-1 shows more electron attraction in triazine ring in 3a-1. A phenyl group which replaced with the amine group has increased electrophilicity of 3a-1 than to 3b-1. Although some contradictions are found in case 3a-5 that it can appropriate to azo-hydrazone tautomerism that it will be discussed in the tautomerism section. 3.4.3. Optimized geometries of azo-hydrazone tautomeric forms The optimized ground state geometries of the dyes in azo-hydrazone tautomeric forms are shown in figures 6 and 7. Figure 7. Ground state optimized structure of dyes 3a series in their azo and hydrazone tautomeric forms Optimized ground state geometries of the compounds in azo forms are almost planar such as 3a-1 and 3a-2 which show a mild dihedral angular twist less than 5 ° at N15-N14-C11-N12 and at N7-N14-C9-C14. All hydrazone forms show a dihedral angle twist by near 30 ° which follows no trend. Optimized bond lengths of the synthesized triazine azo dyes (3a and 3b) have been calculated. The O-H bond lengths of azo forms for all of the naphtholic series (3a-1, 3a-2, 3b-1 and 3b-2) is 0.960 Ã…. Similarly, the N-H bond lengths are 1.015 Ã… for 3a-1 and 3a-2 and 1.000 Ã… for 3b-1 and 3b-2. This calculated information shows no significant trend to determine azo-hydrazone tautomerism but the obtained N-N bond can signify the single-double bond character of the bond. The N-N bond length in hydrazone form falls shorter to the model value of 1.400 Ã… for single bond.[21] N-N bond length in 3a and 3b azo series are 1.232 Ã… and this bond length in 3a and 3b hydrazone forms are 1.400 Ã… except in 3a-5 which N-N bond length in hydrazone form is 1.330 Ã… and this confirms our 1H NMR observation in the existence of 3a-5 in both azo-hydrazone forms in significant ratio, while in other compounds this rate of ratio is not impressive. 3.4.4. Calculated energies of azo-hydrazone tautomeric forms The free energies (E/hartree) and relative energies (ΆE/ kJmol-1) of the synthesized dyes in both azo and hydrazone forms calculated using the B3LYP/6-311G (d,p) level to check theoretical stability difference between tautomeric forms and the values tabulated in Table 5. Contrary to this expectation that hydrazone forms have relative stability than azo tautomers,[15,22] in our TDDFT calculations, only hydrazone form of 3a-1 shows more relative stability than the same of azo form by 26.26 kJmol-1. 2-naphtholic dyes 3a-2 and 3b-2 show a significant stability in azo forms than hydrazone forms by 1260.48 and 498.94 kJmol-1, respectively. In the other compounds there is no difference between the stability of azo and hydrzone form and it shows that in comparison to experimental data, there is no notable accordance in TDDFT structures energy. 4. Conclusion In summary, we have successfully developed an efficient protocol to stabilize nitrous acid by supporting on polyvinylpolypyrrolidone (PVPP). Synthesized PVPP-HNO2 confirmed by simple titration and FT-IR analysis. The TGA results show that the supported system has acceptable thermal stability. In the following, we have synthesized nine heterocyclic triazine azo dyes and they were confirmed by FT-IR, 1H NMR, and mass spectral analysis. UV-Visible spectral analysis was compared with calculated data. TDDFT calculations were performed showing enough adaption with experimental observations. The optimized structure of azo and hydrazone form using B3LYP/6-311 G(d,p) basis set of calculation shows that azo is more stable form in all of the synthesized dyes except 3a-5, which exist in both azo and hydrazone forms. Acknowledgement.   We are thankful to the Yasouj University for partial support of this work. References T. Turney, G. Wright, Chem. Rev. 1959, 59, 497. N. Suzuki, Y. Kaneko, T. Nomoto, Y. Izawa, Chem. Commun. 1984, 22, 1523. M. Mokhtary, S. Refahati, Dyes Pigments 2013, 99, 378. M. Nogami, Y. Sugiyama, T. Kawasaki, M. Harada, Y. Morita, T. Kikuchi, Y. Ikeda, J. Radioanal. Nucl. chem. 2010, 283, 541. H. S. Bhatti, S. Seshadri., Color. Tech. 2004, 120, 151. M. Ghasemian, A. Kakanejadifard, F. Azarbani, A. Zabardasti, S. Shirali, Z. Saki, S. Kakanejadifard, Spectrochim. Acta A. 2015, 138, 643. I. M. Awad, Phosphorus Sulfur 1996, 114, 17. G. Powis, M. Seewald, D. Melder, M. Hoke, C. Gratas, T. Christensen, D. E. Chapman, Cancer Chemoth. Pharm. 1992, 31, 223. W. Hua, E. R. Bennett, R. J. Letcher, Water Res. 2006, 40, 2259. M. A. Satam, R. K. Raut, N. Sekar, Dyes Pigments 2013, 96, 92. D. R. Patel, K. C. Patel, Dyes Pigments 2011, 90, 1. A. LyÄ ka, Collect. Czech. Chem. C. 1983, 48, 3104. Y. Do Kim, J. H. Cho, C. R. Park, J. H. Choi, C. Yoon, J. P. Kim, Dyes Pigments 2011, 89, 1. H. Pinheiro, E. Touraud, O. Thomas, Dyes Pigments 2004, 61, 121. P. G. Umape, V. S. Patil, V. S. Padalkar, K. R. Phatangare, V. D. Gupta, A. B. Thate, N. Sekar, Dyes Pigments 2013, 99, 291. K. J. Siebert, P. Y. Lynn, J. Agr. Food. Chem. 1997, 45, 4275. M. Frisch, G. Trucks, H. Schlegel, G. Scuseria, M. Robb, J. Cheeseman, Gaussian 03, revision C. 02 2008. G. W. Drake, Springer handbook of atomic, molecular and optical physics, Springer Science Business Media 2006. R. G. Pearson, J. Mol. Struc-Theochem. 1992, 255, 261. P. K. Chattaraj, S. Giri, Annu. Rep. Prog. Chem., Sect. C: Phys. Chem. 2009, 105, 13. Y. Ebead, Dyes Pigments 2012, 92, 705. M. S. Deshmukh, N. N. Sekar, Can. Chem. Trans. 1, 2013, 305.

The Role of Magnocellular Cells in Dyslexia Essay -- Dyslexia Learning

The Role of Magnocellular Cells in Dyslexia Dyslexia is a defined as a learning disability characterized by problems in expressive or receptive, oral or written language. Derived from the Greek words "dys" (poor or inadequate) and "lexis" (words or language), dyslexia and other learning disabilities affect about 15% of the population. (What is dyslexia!) Dyslexia itself can manifest itself in many different ways. People with dyslexia do not see words "backwards" or have other vision problems. Many dyslexics are gifted with outstanding musical abilities, or the ability to solve three-dimensional puzzles with little difficulty. (What is dyslexia!) It is not representative of a below average mind and is not caused by behavioral or social problems. Dyslexia is caused by differences in the function and structure of certain areas of the brain. (What is dyslexia!) Because of this, Dyslexia can not be cured and will never be outgrown. Appropriate teaching methods are taught to help those with dyslexia overcome their weakness by using their strengths. Understanding how this disability works and where it stems from can only help in the search for beneficial teaching techniques. Because there are many different aspects of dyslexia, very few dyslexics show all the signs of the disorder. Understanding some of the more devastating symptoms of the disorder provide a strong base for research in the area. Dyslexics may have difficulty encoding words, not be able to recognize sequences of numbers or of letters in words, either when read or written, or not be able to fully interpret instructions that they have been given. Imagine a person driving down the road who cannot distinguish between a sign that says 15 mph and 51 mph. Or a person wh... ... http://cognitrn.psych.indiana.edu/busey/idloc/idloc.html Cornelissen, P.L. (1998). Coherent motion detection and letter position encoding. Vision Research Issue 38, 2181-2191. Cornelissen, P.L. (1998). Magnocellular visual function and children’s single word reading. Vision Research Issue 38, 471-482. Newman, Renee (1998, April). Dyslexia: Explanations from science. [ 8 paragraphs.] Dyslexia and Dyscalculia Support Services of Shiawassee County available: http://www.shianet.org/~reneenew/dysl.html Ridder, W.H. 3rd (1997). Not all dyslexics are created equal. Optometry and Visual Sciences, 74 (3), 99-104. Skottun, B. C. (1997). Some remarks on the magnocellular deficient theory of dyslexia. Vision Research Issue 37, 965-966. What is Dyslexia!. [3 paragraphs]. Discover Technology [Online]. Available: http://discovertechnology.com/whatisdyslexia.html

Examine Eliot’s treatment of women in Prufrock, Preludes, Portrait of E

Examine Eliot’s treatment of women in Prufrock, Preludes, Portrait of a Lady and Rhapsody on a Windy Night In all four of the poems; ‘Prufrock’, ‘Preludes’, ‘Portrait of a Lady’ and ‘Rhapsody on a Windy Night’, Eliot makes references to women. Eliot seems to treat women almost as objects to either be looked at with wonder and, at times, fascination or as objects to be scorned upon. In all of the poems Eliot makes the voice of the poem slightly distanced from the women and this, to me, makes the women seem almost untouchable. When looking at the poem ‘Prufrock’ we must first notice that the full title is ‘The Love Song of J.Alfred Prufrock.’ This title seems almost ironic as, after reading the poem, we realise that the poem is not a love song at all. The title is beauteous however, like the women Eliot makes reference to in the poem; â€Å"In the room the women come and go / Talking of Michelangelo.† This small, non-descriptive mention of women tells us much about Eliot’s perception of women in ‘Prufrock.’ These two lines, presented to us almost like a chorus, interrupt the flow of the poem, which is perhaps what women did in Eliot’s life. These lines also show Eliot’s fascination with women as women were less educated than men around 1910 when ‘Prufrock’ was conceived, so for these women to talk of Michelangelo is almost shocking and something to be marvelled upon. In Prufrock, I believe Eliot is concerned with the high society of women and the poem shows his fascination with them. The tone of ‘Prufrock’ is not bitter towards the women, nor does it celebrate them, it merely comments on the women and Eliot seems to give a fairly neutral view of women. ‘Portrait of a Lady’ is another poem in which Eliot ex... ...apsody on a Windy Night’. By appealing to our senses, Eliot draws us in to his poetry up to a point where we can almost smell exactly what he is describing, which brings us closer to the women in his poems. Between the four poems â€Å"Prufrock†, â€Å"Portrait of a Lady†, â€Å"Preludes† and â€Å"Rhapsody on a Windy Night† Eliot provides us with a rounded view of women. He describes the beautiful and untouchable side of them in ‘Prufrock’, the darker, more sordid side of women in ‘Preludes’ and ‘Rhapsody on a Windy Night’ with a description of how false women can be in ‘Portrait of a Lady’. Eliot’s imagery is effective in the poems, as by using it he justifies his reasons for describing the women in the way he does. I feel that Eliot describes women in the way in which he views them, drawing from personal experiences and what he takes from poets who have gone before him.

plotlear Parallel Plots of Shakespeares King Lear Essay examples --

The Parallel Plots of Shakespeare's King Lear   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   Many works of literature contain parallel plots in which similar actions taken by various characters precipitate identical results.   Upon careful examination, it is evident that â€Å"such plots exist in Shakespeare's play King Lear with the deaths of King Lear, Cordelia, Edmund, and Goneril, among others† (Curry 17).   The betrayal of a commitment to an authority figure is the cause behind each of the above characters' death.   Likewise, the consistent loyalty of Kent, the Fool, and Edgar is rewarded when they outlive their traitorous peers. King Lear, who as a divine-right king derives his power from God, betrays God's will when he transfers his kingdom to his daughters, Reagan and Goneril.   When Lear states that his purpose in doing so is "To shake all cares and business from our age, / Conferring them on younger strengths while we / Unburdened crawl toward death." (Shakespeare 2) he declares his intention to delegate his power so that he is no longer bothered with great responsibilities.   In this self-serving act, Lear is unfaithful to God, whose wish it was for Lear to rule for a lifetime.   Later, God's wrath is apparent in Act III Scene II when Lear speaks to a tempest, a manifestation of God's anger at the strife within the kingdom, and tells it to "Rumble thy bellyful! Spit, fire! Spout rain! / Nor rain, wind, thunder, fire are my daughters" (Shakespeare 60).  Ã‚   Evidently, upon seeing the tempest, Lear is aware that he made a mistake and betrayed God's trust.   In speaking to the tempest, he asks for God to correct the situation by causing Reagan and Goneril to fall from power.   As a result of his unfaithfulness to God, Lear dies of a broken heart in the end of ... ...the conclusion of the play.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   As is by now apparent, there are a multitude of parallel plots within Shakespeare's play King Lear.   In each plot, a character's breach of loyalty condemned the character to certain death in the final scene of the play.   Several of the characters who exhibited treachery and later died were King Lear, Cordelia, Edmund, and Goneril.   Accordingly, Kent, the Fool, Edgar, and Albany all survived the play because they did not cast aside their loyalties. Works Cited and Consulted Bradley, A.C. Shakespearean Tragedy. Macmillan & Co., 1965 Curry, Walter. Studies of the Structure of Shakespeare. London: Mass Peter  Smith, 1968.  Ã‚   Shakespeare, William. The Tragedy of King Lear.   Ed. Russell Fraser.   New York: Penguin, 1998. Webster, Margaret. Shakespeare Without Tears. Greenwich: Fawcett Publications, Inc., 1996.

Race and Ethnicity in Childhood Obesity Essay

Many early life risk factors for childhood obesity are more prevalent among blacks and Hispanics than among whites and may explain the higher prevalence of obesity among racial/ethnic minority children. Eliminating racial/ethnic disparities in health and health care is a national priority, and obesity is a prime target. During the last 30 years in the United States, the prevalence of obesity among children has dramatically increased, sparing no age group. Obesity in childhood is associated with adverse cardio-metabolic outcomes such as hypertension, hyperlipidemia, and type II diabetes and with other long-term adverse outcomes, including both physical and psychosocial consequences. By the preschool years, racial/ethnic disparities in obesity prevalence are already present, suggesting that disparities in childhood obesity prevalence have their origins in the earliest stages of life. Several risk factors during pregnancy are associated with increased risk of offspring obesity, including excessive maternal gestational weight gain, gestational diabetes, and smoking during pregnancy, antenatal depression, and biological stress. During infancy and early childhood, rapid infant weight gain, infant feeding practices, sleep duration, child’s diet, physical activity, and sedentary practices are associated with the development of obesity. Studies have found substantial racial/ethnic differences in many of these early life risk factors for childhood obesity. It is possible that racial/ethnic differences in early life risk factors for obesity might contribute to the high prevalence of obesity among minority preschool-age children and beyond. Understanding these differences may help inform the design of clinical and public health interventions and policies to reduce the prevalence of childhood obesity and eliminate disparities among racial/ethnic minority children. Race and Ethnicity in Childhood Obesity Race is a group whose inherited physical characteristics distinguish it from other groups. Races refer to broad division of people based on their biological characteristics such as color of skin, color of hair and their facial features. These differences developed among humans in prehistoric times due to different groups of people developing in different parts of the world isolated from each other. Originally all humans in the world belonged to one of the other of these pure races. However in today’s world it is difficult to find people of that time. Most of the people living now have mixed racial ancestry. Ethnicity refers to the common characteristics of a group of people that distinguish them from most other people of the same society. Ethnicity is based on commonality of ancestry, culture, language, nationality, or religion, or a combination of these things. Biological characteristics that play a part in racial differences may be visible in an ethnic group, but these characteristic do not form a criteria for defining an ethnic group. Although childhood obesity is increasing in all ethnic and racial groups, its prevalence is higher in nonwhite populations. The reasons for the differences in prevalence of obesity among groups are complex, likely involving genetics, physiology, culture, socioeconomic status, environment and interactions among these variables as well as others not fully recognized. The relationship between race and ethnicity in childhood obesity is that obesity disproportionately affects certain minority youth populations. NHANES found that African American and Mexican American adolescents ages 12-19 were more likely to be overweight, at 21 percent and 23 percent respectively, than non-Hispanic White adolescents (14 percent). In children 6-11 years old, 22 percent of Mexican American children were overweight, whereas 20 percent of African American children and 14 percent of non-Hispanic White children were overweight. In addition to the children and teens that were overweight in 1999-2002, another 15 percent were at risk of becoming overweight. In a national survey of American Indian children 5-18 years old, 39 percent were found to be overweight or at risk for overweight. In most of the states examined, blacks had the highest prevalence (number of existing cases in a defined group of people during a specific time period) of obesity, followed by Hispanics, and then whites. Greater prevalence’s of obesity for non-Hispanic blacks and whites were found in the Midwest and South. Among Hispanics lower prevalence was observed in the Northeast compared to other regions. At least three reasons may account for the racial and ethnic differences in obesity. First, racial and ethnic groups differ in behaviors that contribute to weight gain; second explanation may be differences in individual attitudes and cultural norms related to body weight. A third explanation may be differences in access to affordable, healthful foods and safe locations to be physically active; this limited access may negatively impact diet and physical activity levels. An ethnic group as subpopulations is that low -income and some racial and ethnic subpopulations are more likely to suffer from obesity. Inequities in the physical and social environment may contribute to disparities in pediatric obesity, but there is little empirical evidence to date. This study explored whether neighborhood-level socioeconomic factors attenuate racial and ethnic disparities in obesity among youth in the USA and whether individual-level socioeconomic status (SES) interacts with neighborhood deprivation. In addition, although some of the risk factors for obesity are relatively ubiquitous in settings where American children and youth spend their time in the mall or at home, epidemiologic evidence shows that African-American, Hispanic/ Latino, American Indian/Alaska. Native, and Pacific Islander populations and children experiencing poverty are more likely to live in environments with inadequate support for health-promoting behaviors. Assessing the impact of these different environments presents an enormous challenge for tracking progress against obesity in diverse populations. Racial/ethnic minority children bear a disproportionate share of the burden of obesity and its related comorbidities. The degree of obesity also differs among racial/ethnic minority children. Compared to non-Hispanic white children, non-Hispanic black girls and Hispanic boys had almost 2-fold greater odds of being severely obese. The urban populations of the United States are at a higher risk for obesity than their suburban and rural counterparts. The ethnicity of the urban residents plays a factor in their obesity. In the USA the prevalence of overweight among children aged 4–12 years rose twice as fast in Hispanic and African–American groups compared with white groups over the period 1986–1998. The socioeconomic aspect of the urban area neighborhoods is also a larger factor in the obesity of American urban youth. Culture can influence the utilization of health services; affecting the likelihood that childhood obesity can be prevented or effectively treated in specific ethnic groups. Although physical activity is obviously important in energy balance, intensive physical activity interventions in obese children have produced only small changes in body weight, with somewhat greater changes in metabolic and cardiovascular indexes. Obesity is disproportionately prevalent among racial/ethnic minority children and recent trends suggest these disparities are widening. Our findings suggest that modifiable risk factors throughout the life course, including factors during infancy and early childhood, as well as social conditions in childhood and trans-generational obesity, are critical to understanding how disparities in childhood obesity arise. They also imply that efforts to eliminate racial/ethnic disparities in childhood obesity should focus on preventing these early life risk factors within the socio-environmental context in which they occur. Studies of race and health frequently invoke racism, prejudice, and discrimination as possible reasons for high levels of morbidity and mortality among black and among other racial and ethnic minorities. Obesity is highly stigmatized in our society. Overweight and obese individuals are vulnerable to negative bias, prejudice and discrimination in many different settings, including the workplace, educational institutions, and health care facilities and even within interpersonal relationships. Despite the increasing prevalence of obesity, it appears that incidences of weight discrimination are only becoming worse. Obesity now affects one in five children in the United States. Discrimination against overweight children begins early in childhood and becomes progressively institutionalized. Because obese children tend to be taller than their no overweight peers, they are apt to be viewed as more mature. The inappropriate expectations that result may have an adverse effect on their socialization. References Reilly JJ, Armstrong J, Dorosty AR, et al. Early life risk factors for obesity in childhood: cohort study. BMJ. 2005; 330(7504): 1357 http://pediatrics. aappublications. org/content/125/4/686. full Kimbro RT, Brooks-Gunn J, McLanahan S. Racial and ethnic differentials in overweight and obesity among 3-year-old children. Am J Public Health. 2007; 97(2): 298–305 Wang YC, Gortmaker SL, Taveras EM. Trends and racial/ethnic disparities in severe obesity among US children and adolescents, 1976-2006. International journal of pediatric obesity : IJPO : an official journal of the International Association for the Study of Obesity. 2010 Mar 17; http://www. ncbi. nlm. nih. gov/pmc/articles/PMC3835398/ http://www. ncbi. nlm. nih. gov/books/NBK24680/ Puhl, R. M. , Andreyeva, T. , & Brownell, K. D (2008). Perceptions of weight discrimination: prevalence and comparison to race and gender discrimination in America. International Journal of Obesity. doi: 10. 1038/ijo. 2008. 22 http://www. obesityaction. org/educational-resources/resource-articles-2/weight-bias/weight- discrimination-a-socially-acceptable-injustice.